Journal title
عنوان نشریه
Quarterly Journal of Science Kharazmi University
Literature & Humanities
http://jsci.khu.ac.ir
1
admin
doi
fa
jalali
1387
3
1
gregorian
2008
6
1
18
45
online
1
fulltext
fa
تهیه اپوکسی الکل از سیس و ترانس 2- (1- سیکلو هگزنیل) سیکلو هگزانول و2-سیکلوهگزیلیدن سیکلوهگزانون
Preparation of epoxy alcohols from cis and trans 2-(1-cyclohexenyl cyclohexanol and 2-cyclohexylidene cyclohexanone
از اپوکسیداسیون سیس و ترانس2-(1- سیکلوهگزنیل) سیکلوهگزانول(a4وb4) دو دیاستریو ایزومر( 5و6) بهدست میآید. از سوی دیگر از2- سیکلوهگزیلیدن سیکلوهگزانون(2) به دو روش ترکیب اپوکسی الکل(4) بهدست میآید.
Epoxyalcohols are useful intermediates in complex organic synthesis, and recently they have been recognized as versatile intermediates for synthesis of natural products. The treatments of cis and trans 2-(1-cyclohexenyl) cyclohexanol, separately with paranirto perbenzoic acid gave the corresponding 2-(1- cyclohexenyl) cyclohexanol oxide. On the other hand, 2-cyclohexylidene cyclohexanol oxide was prepared in two ways. The structure of all the compounds confirmed via IR, NMR spectroscopy, and position of hydrogen bonding was examined with IR spectroscopy. Nucleophilic opening of the corresponding compounds by various nucleophilic is under study.
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