Volume 18, Issue 45 (No.1&2-صفحات انگلیسی از 192 تا 212 2008)
2008, 18(45): 905-910 |
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Preparation of epoxy alcohols from cis and trans 2-(1-cyclohexenyl cyclohexanol and 2-cyclohexylidene cyclohexanone. Journal title 2008; 18 (45) :905-910
URL: http://jsci.khu.ac.ir/article-1-1208-en.html
URL: http://jsci.khu.ac.ir/article-1-1208-en.html
Abstract: (4002 Views)
Epoxyalcohols are useful intermediates in complex organic synthesis, and recently they have been recognized as versatile intermediates for synthesis of natural products. The treatments of cis and trans 2-(1-cyclohexenyl) cyclohexanol, separately with paranirto perbenzoic acid gave the corresponding 2-(1- cyclohexenyl) cyclohexanol oxide. On the other hand, 2-cyclohexylidene cyclohexanol oxide was prepared in two ways. The structure of all the compounds confirmed via IR, NMR spectroscopy, and position of hydrogen bonding was examined with IR spectroscopy. Nucleophilic opening of the corresponding compounds by various nucleophilic is under study.
Keywords: h
Published: 2008/06/15
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